AccScience Publishing / MSAM / Volume 4 / Issue 4 / DOI: 10.36922/MSAM025220037
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ORIGINAL RESEARCH ARTICLE

3D-printing advanced ZIF-67@aluminum phosphate/Al2O3 ceramic catalyst by aluminum phosphate-assisted surface bonding

Yuxiong Guo1,2† ,  Shengcai Wu2,3† ,  Peiqing La1* ,  Dekai Zhou4 ,  Zhongying Ji2* ,  Xiaolong Wang2,3
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1 State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metal, Lanzhou University of Technology, Lanzhou, Gansu, China
2 State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, Gansu, China
3 School of Chemistry and Chemical Engineering/State Key Laboratory Incubation Base for Green Processing of Chemical Engineering, Shihezi University, Shihezi, Xinjiang, China
4 State Key Laboratory of Robotics and Systems, Harbin Institute of Technology, Harbin, Heilongjiang, China
†These authors contributed equally to this work.
MSAM 2025, 4(4), 025220037 https://doi.org/10.36922/MSAM025220037
Received: 27 May 2025 | Revised: 30 June 2025 | Accepted: 4 July 2025 | Published online: 21 August 2025
© 2025 by the Author(s). This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution 4.0 International License ( https://creativecommons.org/licenses/by/4.0/ )
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Abstract

The 3D-printed ceramic catalyst has a broad range of application prospects. Notably, the ZIF-67-loaded 3D-printed ceramic catalyst demonstrates exceptional catalytic performance and a high degree of structural design flexibility. However, the ceramics prepared by the direct loading of ZIF-67 onto ceramic substrates during 3D printing show insufficient catalytic stability. In this study, aluminum phosphate (AP) was used as a binder to enhance the adhesion between ZIF-67 and the Al2O3 ceramic support surface, thereby reducing ZIF-67 shedding and preventing the degradation of the catalytic performance of the 3D-printed ceramic catalyst. Consequently, after six cycles, the conversion rate of 4-nitrophenol with ZIF-67/Al2O3 decreased by 31%, whereas that with ZIF-67@AP/Al2O3 decreased by only 5.4%. The reasons for the high catalytic stability of ZIF-67@AP/Al2O3 were comprehensively and meticulously investigated. The proposed synthesis strategy, which utilizes AP to facilitate the bonding of ZIF-67 to the Al2O3 ceramic scaffold, offers a novel approach for enhancing the catalytic stability of 3D-printed ceramic catalysts loaded with active species through self-growth methods. This approach is expected to guide future research on efficient catalytic systems for various applications.

Graphical abstract
Keywords
Direct ink writing
Ceramic catalyst
ZIF-67
3D printing
Funding
The authors gratefully acknowledge the financial support from the National Key Research and Development Program of China (2023YFE0209900), the Strategic Priority Research Program of the Chinese Academy of Sciences (XDB0470303), the National Key Research and Development Program of China (2022YFB4600101), the Central Government to Guide Local Technology Development Program (23ZYQA315), and the Oasis Scholar of Shihezi University.
Conflict of interest
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
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Materials Science in Additive Manufacturing, Electronic ISSN: 2810-9635 Published by AccScience Publishing
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